How to Injection molding of liquid silicone rubber
*Liquid silicone rubber is a high purity platinum cured silicone with low compression set, great stability and ability to resist extreme temperatures of heat and cold ideally suitable for production of parts, where high quality is a must. Due to the thermosetting nature of the material, liquid silicone injection molding requires special treatment, such as intensive distributive mixing, while maintaining the material at a low temperature before it is pushed into the heated cavity and vulcanized.
*Chemically, silicone rubber is a family of thermoset elastomers that have a backbone of alternating silicon and oxygen atoms and methyl or vinyl side groups. Silicone rubbers constitute about 30% of the silicone family, making them the largest group of that family. Silicone rubbers maintain their mechanical properties over a wide range of temperatures and the presence of methyl-groups in silicone rubbers makes these materials extremely hydrophobic, making them suitable for electrical surface insulations.
*Typical applications for liquid silicone rubber are products that require high precision such as seals, sealing membranes, electric connectors, multi-pin connectors, infant products where smooth surfaces are desired, such as bottle nipples, medical applications as well as kitchen goods such as baking pans, spatulas, etc. Often, silicone rubber is overmolded onto other parts made of different plastics. For example, a silicone button face might be overmolded onto an Nylon 6,6 housing.
*Liquid silicone rubbers are supplied in barrels. Because of their low viscosity, these rubbers can be pumped through pipelines and tubes to the vulcanization equipment. The two components are pumped through a static mixer by a metering pump. One of the components contains the catalyst, typically platinum based. A coloring paste as well as other additives can also be added before the material enters the static mixer section. In the static mixer the components are well mixed and are transferred to the cooled metering section of the injection molding machine. The static mixer renders a very homogeneous material that results in products that are not only very consistent throughout the part, but also from part to part. This is in contrast to solid silicone rubber materials that are purchased pre-mixed and partially vulcanized. In contrast, hard silicone rubbers are processed by transfer molding and result in less material consistency and control, leading to higher part variability. Additionally, solid silicone rubber materials are processed at higher temperatures and require longer vulcanization times.
*Liquid silicone rubbers are supplied in a variety of containers, from tubes to 55 gallon drums. Because of their viscous nature, these liquids are pumped at high pressures (500 - 5000 psi) based on the durometer of the material. The raw materials are shipped in two separate containers (known in the industry as a kit) identified as "A" and B" compounds, with the "B" side usually containing the catalyst, but may vary based on the brand of silicone used. The two (A and B) compounds must be mixed in a 1 to 1 ratio, usually by way of a static mixer, adding pigment during the mixing process before the curing process begins. Once the two components come together the curing process begins immediately. A chiller supplying cold water to jacketed fittings is typically used to retard the curing process prior to the materials introduction to the mold. A color pigment can be added via a color injector used in conjunction with the material pump (closed loop metering system) before the material enters the static mixer section.
*In a cold deck scenario, the 1 to 1 mixed compound is pumped through cooled sprue and runner systems into a heated cavity where the vulcanization takes place. The cold runner and general cooling results in minimal loss of material as the injection occurs directly into the part or cavity, saving on overall material costs and using high consistency rubber.The cooling allows production of LSR parts with nearly zero material valve gate waste, however this does not guarantee a "flash free" finished part. Molds and tooling are varying in design, execution and cost. A good cold runner is expensive as compared to conventional hot runner tooling, and has the potential to provide a high level of performance.
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